Blip.tv recently changed their website and removed download links from the individual videos, they still have an RSS feed with the links tho, but only 100 max are showing, which is problematic for shows with more than 100 episodes.

Using http://blip.tv/the-spoony-experiment/rss as an example, is there a way to make the entire RSS feed appear, more than 100? Or is there a program, or script I could use to find the file links another way?

Failing that, is there a more appropriate forum I could be asking this? I really didn't know what to look for here.

They change the output on their rss feed. That's that feed, there isn't anything else. There won't be any script or program that will expand the feed.

Not sure about any software that will be able to scrape the website for links. Might want to ask on a blackhat website. You also might need a custom script made to do something like that.